46. The correct order of N-compounds in its decreasing order of oxidation states is
(1) HNO3, NH4Cl, NO, N2
(2) HNO3, NO, NH4Cl, N2
(3) HNO3, NO, N2, NH4Cl
(4) NH4Cl, N2, NO, HNO3
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47. Which one of the following elements is unable to form MF63– ion?
(1) B (2) Al
(3) Ga (4) In
48. Considering Ellingham diagram, which of the following metals can be used to reduce alumina?
(1) Mg (2) Zn
(3) Fe (4) Cu
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49. The correct order of atomic radii in group 13 elements is
(1) B < Ga < Al < Tl < In
(2) B < Al < Ga < In < Tl
(3) B < Al < In < Ga < Tl
(4) B < Ga < Al < In < Tl
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50. Which of the following statements is not true for halogens?
(1) All but fluorine show positive oxidation states
(2) All are oxidizing agents
(3) All form monobasic oxyacids
(4) Chlorine has the highest electron-gain enthalpy
51. In the structure of ClF3, the number of lone pair of electrons on central atom ‘Cl’ is
(1) Four (2) Two
(3) One (4) Three
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52.
(a)
(b)
(c)
(d)
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54. Regarding cross-linked or network polymers, which of the following statements is incorrect?
(1) Examples are bakelite and melamine.
(2) They are formed from bi- and tri-functional monomers.
(3) They contain covalent bonds between various linear polymer chains.
(4) They contain strong covalents bonds in their polymer chains.
55. Nitration of aniline in strong acidic medium also gives m-nitroaniline because
(1) In absence of substituents nitro group always goes to m-position.
(2) In electrophilic substitution reactions amino group is meta directive.
(3) Inspite of substituents nitro group always goes to only m-position.
(4) In acidic (strong) medium aniline is present as anilinium ion.
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56. The difference between amylose and amylopectin is
(1) Amylopectin have 1 → 4 α-linkage and 1 → 6 β-linkage
(2) Amylose have 1 → 4 α-linkage and 1 → 6 β-linkage
(3) Amylopectin have 1 → 4 α-linkage and 1 → 6 α-linkage
(4) Amylose is made up of glucose and galactose
57. A mixture of 2.3 g formic acid and 4.5 g oxalic acid is treated with conc. H2SO4. The evolved gaseous mixture is passed through KOH pellets. Weight (in g) of the remaining product at STP will be
(1) 2.8 (2) 3.0
(3) 1.4 (4) 4.4
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58. Which of the following oxides is most acidic in nature?
(1) BaO (2) BeO
(3) MgO (4) CaO
59. Which oxide of nitrogen is not a common pollutant introduced into the atmosphere both due to natural and human activity?
(1) N2O (2) NO2
(3) N2O5 (4) NO
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60. The compound A on treatment with Na gives B, and with PCl5 gives C. B and C react together to give diethyl ether. A, B and C are in the order
(1) C2H5Cl, C2H6, C2H5OH
(2) C2H5OH, C2H5Cl, C2H5ONa
(3) C2H5OH, C2H6, C2H5Cl
(4) C2H5OH, C2H5ONa, C2H5Cl
61.
(1) 3-bromo-2,4,6-trichlorotoluene
(2) o-bromotoluene
(3) m-bromotoluene
(4) p-bromotoluene
62. Hydrocarbon (A) reacts with bromine by substitution to form an alkyl bromide which by Wurtz reaction is converted to gaseous hydrocarbon containing less than four carbon atoms. (A) is
(1) CH3–CH3 (2) CH2=CH2
(3) CH≡CH (4) CH4
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63. Which of the following molecules represents the order of hybridisation sp2, sp2, sp, sp from left to right atoms?
(1) CH2= CH – CH = CH2
(2) CH2= CH – C ≡ CH
(3) HC ≡ C – C ≡ CH
(4) CH3– CH = CH – CH3
64. Which of the following carbocations is expected to be most stable?
(a) (b)
(c) (d)
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65. Which of the following is correct with respect to – I effect of the substituents? (R = alkyl)
(1) – NH2 > – OR > – F
(2) – NR2 < – OR < – F
(3) – NH2 < – OR < – F
(4) – NR2 > – OR > – F
66.
(a)
(b)
(c)
(d)